Bis(acetonitrile-κN)dichlorido(η4-cycloocta-1,5-diene)ruthenium(II) acetonitrile monosolvate
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چکیده
In the title Ru(II) complex, [RuCl(2)(C(8)H(12))(C(2)H(3)N)(2)]·CH(3)CN, the metal ion is coordinated to the centers of each of the double bonds of the cyclo-octa-diene ligand, to two chloride ions (in cis positions) and to two N-atom donors (from MeCN mol-ecules) that complete the coordination sphere for the neutral complex. The coordination about the Ru(II) atom can thus be considered to be octa-hedral with a slightly trigonal distortion. There is also one acetonitrile solvent mol-ecule per mol-ecule which is outside the coordination sphere of the ruthenium atom.
منابع مشابه
Bis(acrylonitrile-κN)dichlorido(η4-cycloocta-1,5-diene)ruthenium(II)
In the title complex, [RuCl(2)(C(8)H(12))(C(3)H(3)N)(2)], the metal ion is coordinated to centers of each of the double bonds of the cyclo-octa-1,5-diene ligand, to two chloride ions (in cis positions) and to two N-atom donors from two acrylonitrile mol-ecules that complete the coordination sphere for the neutral complex. The coordination about the Ru(II) atom can thus be considered octa-hedral...
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